Entrevista Daniel Estulin

Peer Reviewe

The director plan of Säynätsalo: strategies in the urban architecture of Alvar Aalto

Peer Reviewe

General Approach To Compute Phosphorescent OLED Efficiency

Phosphorescent organic light-emitting diodes (PhOLEDs) are widely used in the display industry. In PhOLEDs, cyclometalated Ir(III) complexes are the most widespread triplet emitter dopants to attain red, e.g., Ir(piq)3 (piq = 1-phenylisoquinoline), and green, e.g., Ir(ppy)3 (ppy = 2-phenylpyridine), emissions, whereas obtaining operative deep-blue emitters is still one of the major challenges. When designing new emitters, two main characteristics besides colors should be targeted: high photostability and large photoluminescence efficiencies. To date, these are very often optimized experimentally in a trial-and-error manner. Instead, accurate predictive tools would be highly desirable. In this contribution, we present a general approach for computing the photoluminescence lifetimes and efficiencies of Ir(III) complexes by considering all possible competing excited-state deactivation processes and importantly explicitly including the strongly temperature-dependent ones. This approach is based on the combination of state-of-the-art quantum chemical calculations and excited-state decay rate formalism with kinetic modeling, which is shown to be an efficient and reliable approach for a broad palette of Ir(III) complexes, i.e., from yellow/orange to deep-blue emitters

Thermal equilibration between excited states or solvent effects: unveiling the origins of anomalous emissions in heteroleptic Ru(II) complexes

In this manuscript we present a computational study on the photoluminescence properties of several heteroleptic [Ru(H)(CO)(N^N)(tpp)2]+ complexes (tpp = triphenylphosphine). A special focus is set on disentangling the temperature-dependent emissive properties. Experimentally, when cooling a solution of [Ru(H)(CO)(dmphen)(tpp)2]+ (dmphen = 5,6-dimethyl-1,10-phenanthroline) from room to cryogenic temperature, a partial emission switch from metal-to-ligand charge transfer (3MLCT) to ligand-centered (3LC) phosphorescence is observed, resulting in dual photoluminescence. Two different origins of the anomalous emissions are possible, i.e., thermal equilibration between electronically excited states or different excited state solvent relaxation effects. Our calculations are in favor of the thermally equilibrated scenario. This computational investigation highlights the importance of controlling the temperature-dependent emissive behavior for optoelectronic applications

Phoenix: Secure Computation in an Unstable Network with Dropouts and Comebacks

We consider the task of designing secure computation protocols in an unstable network where honest parties can drop out at any time, according to a schedule provided by the adversary. This type of setting, where even honest parties are prone to failures, is more realistic than traditional models, and has therefore gained a lot of attention recently. Our model, Phoenix, enables a new approach to secure multiparty computation with dropouts, allowing parties to drop out and re-enter the computation on an adversarially-chosen schedule and without assuming that these parties receive the messages that were sent to them while being offline - features that are not available in the existing models of Sleepy MPC (Guo et al., CRYPTO \u2719), Fluid MPC (Choudhuri et al., CRYPTO \u2721 ) and YOSO (Gentry et al. CRYPTO \u2721). Phoenix does assume an upper bound on the number of rounds that an honest party can be off-line - otherwise protocols in this setting cannot guarantee termination within a bounded number of rounds; however, if one settles for a weaker notion, namely guaranteed output delivery only for honest parties who stay on-line long enough, this requirement is not necessary. In this work, we study the settings of perfect, statistical and computational security and design MPC protocols in each of these scenarios. We assume that the intersection of online-and-honest parties from one round to the next is at least 2t+1, t+1 and 1 respectively, where t is the number of (actively) corrupt parties. We show the intersection requirements to be optimal. Our (positive) results are obtained in a way that may be of independent interest: we implement a traditional stable network on top of the unstable one, which allows us to plug in any MPC protocol on top. This approach adds a necessary overhead to the round count of the protocols, which is related to the maximal number of rounds an honest party can be offline. We also present a novel, perfectly secure MPC protocol in the preprocessing model that avoids this overhead by following a more "direct" approach rather than first building a stable network and then using existing protocols. We introduce our network model in the UC-framework, show that the composition theorem still holds, and prove the security of our protocols within this setting

Facial and Meridional Isomers of Tris(bidentate) Ir(III) Complexes: Unravelling Their Different Excited State Reactivity

The use of tris(bidentate) Ir(III) complexes as light active components in phosphorescent organic light-emitting diodes (PhOLEDs) is currently the state-of-the-art technology to attain long-lasting and highly performing devices. Still, further improvements of their operational lifetimes are required for their practical use in lighting and displays. Facial/meridional stereoisomerism of the tris(bidentate) Ir(III) architectures strongly influences their emissive properties and thereto their PhOLEDs performances and operational device stabilities. This work underpins at the first-principles level the different excited state reactivities of facial and meridional stereoisomers of a series of tris(bidentate) Ir(III) complexes, which is found to originate in the presence of distinct triplet metal-centered (3MC) deactivation pathways. These deactivation pathways are herein presented for the first time for the meridional isomers. Finally, we propose some phosphor design strategies

¿Quiero estudiar arquitectura? Curso de orientación universitaria : “taller 0.0 de arquitectura”

El taller pretende responder a la necesidad de acercar la arquitectura a la sociedad. Por otro, quiere mostrar, reflexionar y experimentar la arquitectura de la manera más sencilla posible. También es objetivo del curso anticipar, favorecer que el futuro estudiante se familiarice con el entorno universitario, experimente la manera de trabajar de los estudiantes de arquitectura y conozca de primera mano la experiencia de otros alumnos que estudian o han cursado los estudios recientemente. Se pretende así dar las bases necesarias para que un estudiante de ESO, Bachillerato o Ciclo Formativo pueda responder a la pregunta: ¿quieres estudiar arquitectura? En definitiva, se quieren proporcionar argumentos objetivos para que la decisión de cada estudiante se ajuste a sus intereses, capacidades y condiciones personales.Postprint (published version